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convert conjugated dienes into polymers with different microstructure. 183-185 Alkali metals bring about mainly 1,2 addition in the case of polymerization of 1,3-butadiene. 188 Lithium, however, is an exception since it gives polymers with high 1,4 content.183-185 Dominant 1,2 addition occurs if polymerization is catalyzed by lithium alkyls in ethers. 189 In hydrocarbon solvents, in contrast, 1,4 addition (>90%) prevails with approximately equal amounts of cis and trans units. 19o Sodium-based catalysts, the so-called Alfin systems l91 (e.g., a mixture of sodium allyl, sodium isopropoxide and NaCl), can be used to synthesize very-high-molecularweight polybutadiene with dominating trans content. l92 Lithium or lithium alkyls can be used to convert isoprene to cis-1 ,4-polyisoprene with cis content up to 96% (a structure similar to that of natural rubber), with the remaining part having 3,4 structure.193-195 Similar to the changes observed in the polymerizaton of 1,3-butadiene, the dominant cis-1,4 selectivity changes to 1,2 and 3,4 addition in ethers. 195,196 Change of solvation of Li+ in polar solvents affecting the ionic character of the C-Li bond is considered to be an important factor in bringing about these selectivity changes. The predominant l,4-addition selectivity with lithium in nonpolar solvents is explained by the localization of Li+ to the terminal carbon. Morton et al. found 197 ,198 that lithium is essentially cr-bonded to the terminal carbon (23). In polar solvents the negative charge is delocalized (24), generating a TC-allyl structure that enhances the reactivity of the y-carbon, affording 1,2 addition:

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I use italic type for new terms and for emphasis and boldface type for text that you need to type directly from the computer keyboard.

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Opening an HTML File ............................................................................................................516 Working with Hyperlinks ..........................................................................................................516 Inserting a hyperlink ......................................................................................................517 Using hyperlinks ............................................................................................................518 Using Web Queries....................................................................................................................518

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Figure 21-5: Use Live Data view to make sure your table layout works well with the actual data that appears on the page.

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7423 USSCs USSCs are adherent, spindle-shaped cells and have a size of 20 25 m USSCs are negative for CD14, CD33, CD34, CD45, CD49b, CD49c, CD49d, CD49f, CD50, CD62E, CD62L, CD62P, CD106, CD117, glycophorin A, and HLA-DR USSCs express high levels of CD13, CD29, CD44, CD49e, CD90, CD105, vimentin, and cytokeratin 8 and 18 and express low levels of CD10 and FLK1 (KDR) [K gler o et al, 2004] USSCs can be cultured for >20 passages, equivalent to >40 population doublings, without any spontaneous differentiation USSCs express various transcripts for cytokine receptors, transcription factors, and surface markers including epidermal growth factor receptor, platelet-derived growth factor receptor, insulin-like growth factor receptor, Runt-related transcription factor (Runx1), YB1, CD49e, and CD105.

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Proof : We give the proof only for the case i0(V ) i0(C (0)) i0(C (1)) i0(C ) 0. Equation (7.39) shows that

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